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Polychlorinated Biphenyls

PCBs are synthetic and produced either as a singular congener, as a homogeneous group or as a mixture. Polychlorinated biphenyls (PCBs) are a family of 209 congeners of structurally similar organic chemicals, ranging from oily liquids to waxy solids. Some PCB congeners are dioxin-like and can similarly be toxic and non-toxic. One dioxin-like PCB is 3,4,4',5-Tetrachlorobiphenyl.

Reporting Limits – EPA Method 1668A: 0.2ppt for aqueous, 10ppt for solids, and 200pg/sample for air.

Additional congeners up to and including all 209, as well as total homologs can be reported. Please contact laboratory concerning availability and their typical reporting limits.

Visit US EPA website for more information on PCBs

PCB Congener (IUPAC#)

CAS Number

Structure

WHO List (12)

Full Name

77-TeCB 32598-13-3 3,3’,4,4’

X

3,3',4,4'-Tetrachlorobiphenyl
81-TeCB 70362-50-4 3,4,4’,5

X

3,4,4',5-Tetrachlorobiphenyl
105-PeCB 32598-14-4 2,3,3’,4,4’

X

2,3,3',4,4'-Pentachlorobiphenyl
114-PeCB 74472-37-0 2,3,4,4’,5

X

2,3,4,4',5-Pentachlorobiphenyl
118-PeCB 31508-00-6 2,3’,4,4’,5

X

2,3',4,4',5-Pentachlorobiphenyl
123-PeCB 65510-44-3 2’,3,4,4’,5

X

2,3',4,4',5'-Pentachlorobiphenyl
126-PeCB 57465-28-8 3,3’,4,4’,5

X

3,3',4,4',5-Pentachlorobiphenyl
156-HxCB 38380-08-4 2,3,3’,4,4’,5

X

2,3,3',4,4',5-Hexachlorobiphenyl
157-HxCB 69782-90-7 2,3,3’,4,4’,5’

X

2,3,3',4,4',5'-Hexachlorobiphenyl
167-HxCB 52663-72-6 2,3’,4,4’,5,5’

X

2,3',4,4',5,5'-Hexachlorobiphenyl
169-HxCB 32774-16-6 3,3’,4,4’,5,5’

X

3,3',4,4',5,5'-Hexachlorobiphenyl
189-HpCB 39635-31-9 2,3,3’,4,4’,5,5’

X

2,3,3',4,4',5,5'-Heptachlorobiphenyl
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