PCBs are synthetic and produced either as a singular congener, as a homogeneous group or as a mixture. Polychlorinated biphenyls (PCBs) are a family of 209 congeners of structurally similar organic chemicals, ranging from oily liquids to waxy solids. Some PCB congeners are dioxin-like and can similarly be toxic and non-toxic. One dioxin-like PCB is 3,4,4',5-Tetrachlorobiphenyl.
Reporting Limits – EPA Method 1668A: 0.2ppt for aqueous, 10ppt for solids, and 200pg/sample for air.
Additional congeners up to and including all 209, as well as total homologs can be reported. Please contact laboratory concerning availability and their typical reporting limits.
Visit US EPA website for more information on PCBs
PCB Congener (IUPAC#) |
CAS Number |
Structure |
WHO List (12) |
Full Name |
| 77-TeCB | 32598-13-3 | 3,3’,4,4’ | X |
3,3',4,4'-Tetrachlorobiphenyl |
| 81-TeCB | 70362-50-4 | 3,4,4’,5 | X |
3,4,4',5-Tetrachlorobiphenyl |
| 105-PeCB | 32598-14-4 | 2,3,3’,4,4’ | X |
2,3,3',4,4'-Pentachlorobiphenyl |
| 114-PeCB | 74472-37-0 | 2,3,4,4’,5 | X |
2,3,4,4',5-Pentachlorobiphenyl |
| 118-PeCB | 31508-00-6 | 2,3’,4,4’,5 | X |
2,3',4,4',5-Pentachlorobiphenyl |
| 123-PeCB | 65510-44-3 | 2’,3,4,4’,5 | X |
2,3',4,4',5'-Pentachlorobiphenyl |
| 126-PeCB | 57465-28-8 | 3,3’,4,4’,5 | X |
3,3',4,4',5-Pentachlorobiphenyl |
| 156-HxCB | 38380-08-4 | 2,3,3’,4,4’,5 | X |
2,3,3',4,4',5-Hexachlorobiphenyl |
| 157-HxCB | 69782-90-7 | 2,3,3’,4,4’,5’ | X |
2,3,3',4,4',5'-Hexachlorobiphenyl |
| 167-HxCB | 52663-72-6 | 2,3’,4,4’,5,5’ | X |
2,3',4,4',5,5'-Hexachlorobiphenyl |
| 169-HxCB | 32774-16-6 | 3,3’,4,4’,5,5’ | X |
3,3',4,4',5,5'-Hexachlorobiphenyl |
| 189-HpCB | 39635-31-9 | 2,3,3’,4,4’,5,5’ | X |
2,3,3',4,4',5,5'-Heptachlorobiphenyl |